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Department of Chemical Engineering

Annual Report 2015

8

EU, Norwegian and international industry and other

sources, and spans from fundamental studies of ideal

surfaces to studies of real catalysts and process

development work in small pilot plants.

The Catalysis Group was a research partner in a Centre

for Research-based Innovation (Innovative Natural Gas

Processes and Products – inGAP) in the period 2007-

2015.

Since 2015, the Catalysis Group is heading a new Centre

for Research-based Innovation: industrial Catalysis

Science and Innovation (iCSI) – for a competitive and

sustainable process industry. The main objective of iCSI

is to boost industrial innovation and competitiveness as

well as to provide efficient, low-emission process

technology. The centre director is Professor Hilde J.

Venvik.

AREAS OF RESEARCH

A description of the Catalysis Group as well as further

details of all the projects, are given in our Annual Report

(KinCat).

INDUSTRIAL PROCESS CHEMISTRY

In the iCSI centre, the group is working with industrial

partners to improve catalysts and associated technology

applied to the following industrial processes:

Production of nitric acid (HNO

3

) from ammonia (NH

3

)

Synthesis of polyvinylchloride (PVC) produced by

polymerization of the monomer vinyl chloride (VCM)

Improve the performance of existing formalin

production process technology which is based on the

catalytic oxidation of methanol to formaldehyde

The fact that 85-90% of all chemical production is

catalysis based, illustrates the importance of catalysis to

the economic growth and the life-standard developed

over the previous century. By optimizing the catalytic

process, energy consumption and cost in industrial

processes will be reduced. Catalysis is also key to

enhancing selectivity, an important principle of green

chemistry, since it reduces the formation of by-products

and waste as well as the energy consumption.

DESIGN AND PREPARATION OF NEW CATALYSTS

AND SUPPORTS

The catalytically active material is the key to any catalytic

process, and the preparation of these, highly specialized

functional materials is an important industry.

Understanding the processes involved in the

preparation, and developing improved methods are

therefore central research areas. We work with new

methods for the preparation of supports and catalysts,

as well as the preparation and use of structured,

mesoporous supports. Other areas include core-shell

particles and size and shape-control of metal particles.

CARBON NANOMATERIALS

Carbon nanofibres (CNF) have several interesting

properties such as high resistance to strong acids and

bases, high electric conductivity (similar to graphite),

relatively high surface area and high mechanical

strength. These unique properties lead to a large number

of applications, such as catalyst supports, selective

sorption agents, energy storage, composite materials,

nano-electric and nano-mechanical devices, as well as

field emission devices. The programme includes

synthesis of carbon nanofibres and nanotubes of

different morphology and the use of CNF/CNT in

applications such as heterogeneous catalysis, fuel cells

and conversion and storage of energy. This is done in

collaboration with other groups at NTNU, SINTEF and

Norwegian industry. Replacing noble metals using doped

carbon nanomaterials in fuel cells, dehydrogenation

reactions and in water treatment have been explored in

a European project coordinated by the Catalysis group at

NTNU.

Carbon nanomaterials in energy storage